汪钟凯  
Zhongkai Wang
性    别:
单    位:
林学与园林学院
专业名称:
材料科学与工程
研究方向:
生物质材料与能源
技术职务:
教授
 E-mail:
wangzk6163.com
通讯地址:
安徽省合肥市长江西路130号
邮政编码:
230036

汪钟凯,教授,博士生导师,青年皖江学者,教研室主任。全国天然纤维复合材料专业委员会委员,安徽省材料科学与工程专业合作委员会委员。2009年本科毕业于合肥工业大学,2014年获中国科学技术大学材料加工工程工学博士学位,随后在美国南卡罗来纳大学化学与生物化学系进行博士后研究,20168月起任安徽农业大学教授。主要从事基于农林生物质的高分子新材料领域研究在Accounts of Chemical ResearchAdvanced MaterialsACS NanoGreen Chemistry等国际高水平期刊发表SCI论文29篇,总引用370余次,H指数为122016年起主持国家自然科学基金、安徽省留学回国人才创新项目(重点项目)、青年皖江学者、安徽农业大学高层次人才项目。获得中国发明专利授权2项,申请发明专利2项(其中国际发明专利1项),参与撰写英文专著一部。

教育经历:

2009/9–2014/6, 中国科学技术大学, 材料加工工程,工学博士

2005/9–2009/6, 合肥工业大学, 高分子材料与工程,工学学士

工作经历:

2016/8-至今,安徽农业大学,林学与园林学院材料科学与工程系,教授

2014/7-2016/8,美国南卡罗来纳大学,博士后

 主讲课程
主讲本科生课程《高分子化学与物理》,《高分子化学与物理实验》。
 研究方向

1. 基于农林生物质的新型高分子材料 
1.1基于可再生农林生物质的弹性体 
生物质是一类由植物油脂、萜类和纤维素、半纤维素、木质素等为主要成分构成的天然有机物质。我们的目标是以农林生物质为原料,开发可持续的材料,充分利用自然资源,以减少石油化石对环境的危害。本课题组通过单体设计、高分子拓扑结构裁剪及聚集态结构调控制备了一系列农林生物质基弹性体。

1.2农林生物质基环氧树脂 
环氧树脂应用广泛,但是基于石油资源的环氧树脂对人体和环境都有较大危害。环氧大豆油是环氧树脂潜在的绿色替代产品,目前其产品性能还不足以应用。本课题组提出将油脂制成环氧高分子,随着单个分子上环氧基团的数量的增加,其产品的机械性能将得到大幅提升。 Macromolecular Rapid Communication,2017


1.3农林类生物质基功能聚酰胺 
通过创新的方法,将植物油脂肪酸高效转化为功能性聚酰胺酰胺,通过调节侧基的结构,可有效调控功能性聚酰胺的性能。例如,图中所示的弹性体表现出极高的强度和弹性,说明课题组在新型功能性聚酰胺领域迈出了坚实的一步。 

2 功能性高分子材料 
2.1皮肤仿生 
皮肤具有精致的结构组成和独特的力学性能,人工合成材料还难以模仿。课题组报道一种基于纳米纤维素及弹性的聚戊二烯构筑的独特网络结构,这种新型聚合物可密切模仿人体皮肤的力学性能, 通过调整纤维素含量能模仿不同类型皮肤的性能。ACS Nano, 2015, 9, 271-278


2.2弹性蛋白仿生 
回弹力最高的材料仍然在动物王国,如蜻蜓的节肢弹性蛋白具备极高的弹力。本课题组模仿其微结构,以纤维素和天然橡胶为原料设计了网络结构优异的弹性材料,使之表现出超高弹力、高应变、合理的拉伸强度,能够密切模仿弹性蛋白。ACS Macro Letters, 2016, 5, 220-223.


 
2.3 形状记忆高分子材料 
课题组以纤维素和大豆油为原料,通过简单高效的方法制备了形状记忆功能纳米材料。些材料表现出优异的多重形状记忆功能。这为设计下一代低成本、生物质基、绿色智能新材料提供了新的思路和技术。ACS Macro Letters, 2016, 5, 602-606;Green Chemistry, 2015, 17, 3806-3818.


 科研情况

4. 主持国家自然科学基金面上项目,2018-2021  

3. 主持国家自然科学基金青年科学基金,2017-2019    

2. 主持安徽省留学回国人才创新计划重点项目,2017-2020 

1. 主持安徽农业大学高层次人才引进项目,2016-2020

 获奖情况
青年皖江学者
 论文论著

代表性论文:

2016年8月后

30】 Lingzhi Song, Zhongkai Wang,* Meghan E. Lamm,Liang Yuan,and Chuanbing Tang, Supramolecular Polymer Nanocomposites Derived from Plant Oils and Cellulose Nanocrystals, Macromolecules 2017,DOI: 10.1021/acs.macromol.7b01691.

29】 Zhongkai Wang*, Liang Yuan, Chuanbing Tang, Sustainable Elastomers from Renewable Biomass, Accounts of Chemical Research, 2017, DOI.org/10.1021/acs.accounts.7b00209.

【28】 Zhongkai Wang, Mitra Ganewatta, Chuanbing Tang*, Plant Oil-Derived Epoxy Polymers toward Sustainable Biobased Thermosets. Macromolar Rapid Communication, 2017, 1700009.

27】 Liang Yuan, Zhongkai Wang, Mitra S. Ganewatta, Md Anisur Rahman, Meghan E. Lamm and Chuanbing Tang, A biomass approach to mendable bio-elastomers, Soft Matter, 2017, 13, 1744-6848.

【26】 Mitra S. Ganewatta, Wenyue Ding, Md Anisur Rahman, Liang Yuan, Zhongkai Wang, Nasrollah Hamidi, Biobased Plastics and Elastomers from Renewable Rosin via “Living” Ring-Opening Metathesis Polymerization, Macromolecules, 2016, 49,7155-7164.

【25】 Jifu Wang, Liang Yuan, Zhongkai Wang, Md Anisur Rahman, Yucheng Huang, Tianyu Zhu, Ruibo Wan, Photoinduced Metal-Free Atom Transfer Radical Polymerization of Biomass-Based Monomers, Macromolecules, 2016,49, 7709-7717.

2016年8月前

【24】 Zhongkai Wang, Feng Jiang, Yaqiong Zhang, Yezi You, Zhigang Wang*, Zhibin Guan*, Bioinspired design of nanostructured elastomers with crosslinked soft matrix grafting on the oriented rigid nanofibers to mimic mechanical properties of human skin, ACS Nano, 2015, 9, 271-278.

【23】 Zhongkai Wang, Liang Yuan, Nathan M. Trenor, Laetitia Vlaminck, Stijn Billiet, Amrita Sarkar, Filip E. Du Prez, Morgan Stefik, Chuanbing Tang*, Sustainable thermoplastic elastomers derived from plant oil and their “click-coupling” via TAD chemistry, Green Chemistry, 2015, 17, 3806-3818.

【22】 Zhongkai Wang, Di Wang, Hua Wang, Junjie Yan, Yezi You*, and Zhigang Wang. Preparation of biocompatible nanocapsules with temperature-responsive and bioreducible properties. Journal of Materials Chemistry, 2011, 21, 15950-15956.

【21】 Zhongkai Wang, Liang Yuan, Chuanbing Tang*, Biomass Approach toward Robust, Sustainable, Multiple-Shape-Memory Materials. ACS Macro Leters, 2016, 5, 602−606.

【20】 Zhongkai Wang, Feng Jiang, Zhigang Wang*, and Chuanbing Tang*, Bioinspired design of high resilient elastomers to mimic resilin, ACS Macro Letters, 2016, 5, 220-223.

【19】 Feng Jiang#, Zhongkai Wang#, Yali Qiao, Zhigang Wang*, and Chuanbing Tang*, A novel architecture toward third-generation thermoplastic elastomers by a grafting strategy, Macromolecules, 2013, 46, 4772-4780.

【18】 Zhongkai Wang, Longhai Wang, Jiaotong Sun, Lifen Han, and Chunyan Hong*. In situ generation of bioreducible and acid labile nanogels/microgels simply via adding water into the polymerization system. Polymer Chemistry, 2013, 4, 1694-1699.

【17】 Zhongkai Wang, Yaqiong Zhang, Feng Jiang, Huagao Fang, and Zhigang Wang*, Synthesis and molecular characterization of designed polyisoprene grafted cellulose copolymers, Polymer Chemistry, 2014, 5, 3379-3388.

【16】 Junjie Yan, Zhongkai Wang, Xiangsong Lin, Chunyan Hong*, Haojun Liang, Caiyuan Pan, and Yezi You*. Polymerizing Nonfluorescent Monomers without Incorporating any Fluorescent Agent Produces Strong Fluorescent Polymers. Advanced Materials, 2012, 24, 5617-5624.

【15】 Yuzhi Xu, Liang Yuan, Zhongkai Wang, Perry Wilbon, Chunpeng Wang, Fuxiang Chu and Chuanbing Tang, Lignin and Soy Oil-Derived Polymeric Biocomposites by “Grafting from” RAFT Polymerization, Green Chemistry, 2016,18, 4974-4981.

【14】 Feng JiangYaqiong ZhangZhongkai WangWentao WangZhaohua Xu, and Zhigang Wang*, Combination of magnetic and enhanced mechanical properties for copolymer-grafted magnetite composite thermoplastic elastomers, ACS Applied Materials & Interfaces, 2015, 7 (19), pp 10563-10575.

【13】Yong Zhong, Huagao Fang, Yaqiong Zhang, Zhongkai Wang, Jingjing Yang, and Zhigang Wang*. Rheologically Determined Critical Shear Rates for Shear-Induced Nucleation Rate Enhancements of Poly(lactic acid). ACS Sustainable Chemistry and Engineering, 2013, 1 (6), pp 663–672.

【12】 Liang YuanZhongkai WangNathan M. Trenor, and Chuanbing Tang*, Robust amidation transformation of plant oils into fatty derivatives for sustainable monomers and polymers, Macromolecules, 2015, 48 (5, , , , , ), 1320-1328.

【11】 Liang Yuan, Zhongkai Wang, Nathan M. Trenor, and Chuanbing Tang*, Amidation of triglycerides by amino , , , alcohols and their impact on , , p, , lant oi, l-derived polymers, Polymer Chemistry, 2016, 7, 2790–279.

【10】 Chu Fang, Yaqiong Zhang, Wentao Wang, Zhongkai Wang, Feng Jiang,* and Zhigang Wang*, Fabrication of copolymer-grafted multiwalled carbon nanotube composite thermoplastic elastomers filled with unmodified MWCNTs as additional nanofillers to significantly improve both electrical conductivity and mechanical properties, Ind. Eng. Chem. Res., 2015, 54, 12597-12606.

【9】 Yupeng Liu, Kejian Yao*, Xiaoming Chen, Harry J. Ploehn, Zhongkai Wang, Chunpeng Wang, Fuxia, ng Chu*, Chuanbing Tang*, Sustainable thermoplastic elastomers derived from renewable cellulose, rosin and fatty acids. Polymer Chemistry, 2014, 5, 3170-3181.

【8】 Feng JiangYaqiong ZhangZhongkai Wang, Huagao FangYunsheng DingHangxun Xu, and Zhigang Wang*, Synthesis and characterization of nanostructured copolymer-grafted multiwalled carbon nanotube composite thermoplastic elastomers toward unique morphology and strongly enhanced mechanical properties, Ind. Eng. Chem. Res., 2014, 53, 20154-20167.

【7】Baolong Wang, Zhongkai Wang, Feng Jiang, Huagao Fang and Zhigang Wang*. Synthesis and characterization of MWCNT-graft-polyisoprene via ARGET ATRP. RSC Advances, 2014, 4, 26468-26475.

【6】Yaqiong Zhang, Huagao Fang, Zhongkai Wang, Miao Tang and Zhigang Wang*. Disclosing the formation of ring-banded spherulites for semicrystalline polymers through the double-layer film method. CrystEngComm, 2014, 16, 1026-1037.

【5】Yaqiong Zhang, Zhaohua Xu, Zhongkai Wang, Yunsheng Ding and Zhigang Wang*. Strong enhancements of nucleation and spherulitic growth rates through amplified interfacial effects for immiscible linear polymer/comb-like copolymer double-layer films. RSC Advances, 2014, 4, 20582-20591.

【4】 Feng Jiang, Yaqiong Zhang, Chu Fang, Zhongkai Wang, and Zhigang Wang*, From soft to strong elastomers: the role of additional crosslinkings in copolymer-grafted multiwalled carbon nanotube composite thermoplastic elastomers, RSC Advances, 2014, 4, 60079-60085.

【3】Huagao Fang, Yaqiong Zhang, Jing Bai, Zhongkai Wang, and Zhigang Wang*. Bimodal architecture and rheological and foaming properties for gamma-irradiated long-chain branched polylactides. RSC Advances, 2013, 3, 8783-8795.

【2】Lu Yan, Zhongkai Wang, Junjie Yan, Lifen Han, Qinghui Zhou*, and Yezi You*. Selectively grafting polymer from the interior and/or exterior surfaces of bioreducible and temperature-responsive nanocapsules. Polymer Chemistry, 2013, 4, 1234-1249.

【1】 Yaqiong Zhang, Zhongkai Wang, Feng Jiang, Jing Bai, and Zhigang Wang*. Effect of miscibility on spherulitic growth rate for double-layer polymer films. Soft Matter, 2013, 9, 5771-5778.

代表性著作:

参编《Sustainable Polymers from Biomass》,德国Wiley出版集团,P182。